Region — US. Neutral scientific reference — not offered for sale here.
Cart · 0
Set region
Explore  /  PACAP (Pituitary Adenylate Cyclase-Activating Polypeptide)
Research reference — not for sale

PACAP (Pituitary Adenylate Cyclase-Activating Polypeptide)

F
lead outcome
Neuroprotection / cognitive enhancement in…
grades vary by outcome ↓
Peptide
also called — PACAP-38 · PACAP-27 · pituitary adenylate cyclase-activating polypeptide · ADCYAP1 (gene) · INCI: none
neuropeptide (endogenous)migraine pathophysiologyvasodilationadenylate cyclase signalling

Status: reference entry — not for sale. No dosing, reconstitution, or administration is published (intentional). Neutral scientific reference only. This entry exists partly to correct a common inversion: the validated clinical use of PACAP is as a target to be blocked, not as a compound to be administered.

In brief

PACAP (pituitary adenylate cyclase-activating polypeptide) is an endogenous neuropeptide and one of the most potent known activators of adenylate cyclase, signalling through PAC1, VPAC1 and VPAC2 receptors. It is genuinely important in human physiology and genuinely important in medicine right now — but in a direction that inverts how it is marketed. The best-established human finding is that infusing PACAP-38 causes migraine-like attacks, cranial vasodilation and headache, reproducibly enough to serve as a standard experimental provocation model. Accordingly, the entire clinical programme around PACAP consists of monoclonal antibodies designed to block it: bocunebart (Lu AG09222) met its endpoints in the phase 2 HOPE trial (NEJM 2024) and phase 2b PROCEED, with phase 3 planned. Meanwhile PACAP is sold on research-chemical sites as a neuroprotective or nootropic agent, on the strength of cell and animal studies, with no human efficacy trials of administering it and a well-documented human record of headache when it is given. The neuroprotection literature is real; the human evidence points the other way.

Legal standing, by region
European Union
Not approved

PACAP is not an approved medicine in the EU and holds no marketing authorisation. It is not a permitted cosmetic ingredient of note. Any sale is as a non-medicinal "research" chemical, which does not authorise human use. Note that the clinical programmes in this space are for antibodies that block PACAP, not for PACAP itself.

United Kingdom
Not approved

No marketing authorisation; research status only.

United States · your region
Not FDA-approved

Not approved for any indication and not developed as a therapeutic to administer. The anti-PACAP antibody bocunebart (Lu AG09222) is investigational, with phase 3 planned; approval of an antibody that neutralises PACAP would not constitute approval of PACAP.

International
Not approved anywhere

Approved in no jurisdiction. Used in clinical research primarily as an experimental provocation agent.

Evidence, by outcome
How we grade →

An honest grade per outcome — drawn from the evidence, not any catalogue. Hype and undemonstrated marketing claims grade low.

OutcomeEvidence base · effectGrade
Neuroprotection / cognitive enhancement in humans
This is the use PACAP is marketed for on research-chemical sites, and it has no human clinical support whatsoever. The preclinical neuroprotection literature is real, but it exists alongside a robust human literature showing that administering PACAP causes headache and vasodilation. Marketing that cites the neuroprotection papers while omitting the provocation studies is presenting half a file.
No completed human efficacy trials. Preclinical literature reports neuroprotective and neurotrophic effects in cell and animal models, and PACAP-BDNF signalling has been explored observationally in depression (NCT00944996, a basic-science study, not a treatment trial). · Not demonstrated in humans.
F
PACAP as a migraine TRIGGER (provocation studies in humans)
This is the best-established human effect of exogenous PACAP, and it is an adverse one. Anyone considering PACAP as something to administer should start here: in controlled human studies, giving it causes headache.
Amin FM, et al. Investigation of the pathophysiological mechanisms of migraine attacks induced by pituitary adenylate cyclase-activating polypeptide-38. Brain. 2014;137:779-794. Al-Karagholi MA, et al. PACAP38-induced migraine attacks are independent of CGRP signaling: a randomized controlled trial. J Headache Pain. 2025;26:79. Christensen RH, et al. Activation and sensitization of meningeal nociceptors by PACAP-38. Brain. 2026;149:897-907. Also demonstrated in post-traumatic headache (randomised, double-blind, placebo-controlled crossover infusion trial, PMC10994530). · Intravenous PACAP-38 reliably induces migraine-like attacks, cranial vasodilation and headache in humans — reproducibly enough that it is used as a standard experimental provocation model.
A
Blocking PACAP for migraine prevention (anti-PACAP antibodies)
Note carefully what this grade applies to: **removing** PACAP, not supplying it. The A-grade evidence here belongs to monoclonal antibodies that block the peptide. It is not evidence for PACAP itself, and it points the opposite way.
Lu AG09222 (bocunebart, Lundbeck) — phase 2 HOPE trial published in NEJM 2024: 750 mg IV reduced monthly migraine days by 6.2 versus 4.2 for placebo (difference -2.0 days; 95% CI -3.8 to -0.3; P=0.02). Phase 2b PROCEED (NCT06323928, ~498 participants across Europe, Japan and the US) met its primary endpoint, with results presented at AHS 2026; pivotal phase 3 planned. LY3451838 (Eli Lilly), a PACAP-neutralising antibody, showed reductions in monthly migraine headache days in phase 2 in treatment-resistant migraine (Cephalalgia 2025). AMG 301, an anti-PAC1 receptor antibody, was tested in phase 2 (Cephalalgia 2021). · Neutralising PACAP reduces migraine frequency — a validated therapeutic mechanism, working independently of the CGRP pathway targeted by existing preventives.
A
Adenylate cyclase / PAC1 receptor signalling (mechanism level)
Mechanistic grade A describes what the molecule does in a dish and in normal physiology. It says nothing about benefit from administering it, and in this case the potency is part of why exogenous administration produces such reliable vascular and nociceptive effects.
Miyata et al. (1989) original characterisation — PACAP-38 stimulates cAMP production in rat anterior pituitary cells roughly 1000-fold more potently than VIP, with EC50 in the low picomolar range. Receptor pharmacology across PAC1, VPAC1 and VPAC2 is well mapped (Walker CS, et al. Br J Pharmacol. 2014;171:1521-1533). · One of the most potent known activators of adenylate cyclase; well-characterised, physiologically important signalling peptide.
A
Human safety of exogenous administration
There is no chronic-administration safety dataset in humans, because no one is developing PACAP as a therapy to administer. The acute profile is not benign, and gray-market material carries the usual separate purity and sterility risks.
Characterised chiefly through provocation studies, in which PACAP-38 is infused deliberately to induce symptoms, and through the comparator arms of antibody development work (e.g. Rasmussen NB, et al. J Headache Pain. 2023;24:60, on PACAP38- and VIP-induced vasodilation, heart rate increase and headache in healthy subjects). · Documented acute effects in healthy humans: cranial vasodilation, increased heart rate, flushing, and headache — including migraine-like attacks in susceptible individuals.
Disclosure

Vallydia sells its own cosmetic serums, and some ingredients graded here belong to the same categories as those products. Grades are drawn from the published evidence by the method we publish, and applied to our own ingredients on the same terms — our copper-peptide serum is graded no more kindly than the peptides it competes with. We disclose the interest so you can weigh it.

Trade names shown here (for example Matrixyl, Argireline, Syn-Ake) are the property of their respective owners and are used only to identify the ingredient under discussion. Their appearance implies no affiliation with, or endorsement by, the proprietor.

Evidence changes

Get notified if this changes

We track new research and update these grades as the evidence moves. Leave your email and we'll tell you if the evidence for PACAP (Pituitary Adenylate Cyclase-Activating Polypeptide) changes - nothing else.

One ingredient, one purpose. No marketing, no sharing. Unsubscribe anytime. See our privacy policy.

Identity

PACAP — pituitary adenylate cyclase-activating polypeptide — is an endogenous neuropeptide existing in two active forms, PACAP-38 (38 amino acids, the dominant form in tissue) and PACAP-27. It belongs to the VIP/secretin/glucagon superfamily and shares substantial sequence identity with vasoactive intestinal peptide (VIP), with which it shares two of its three receptors. It is encoded by the ADCYAP1 gene and is expressed widely across the central and peripheral nervous system, including the trigeminal system that matters for headache.

It signals through three G-protein-coupled receptors: PAC1, which is PACAP-selective, and VPAC1 and VPAC2, which respond to both PACAP and VIP. That receptor split is central to the drug development story, since selectivity determines which pathway an antibody hits.

Development & history

  • 1989: Isolated and characterised by Miyata and colleagues from ovine hypothalamus, named for its extraordinary potency in stimulating adenylate cyclase in pituitary cells — roughly a thousandfold more potent than VIP in that assay.
  • 1990s–2000s: Extensive preclinical work established roles in neurodevelopment, neuroprotection, circadian regulation, stress response and vasodilation. This is the literature that research-chemical marketing draws on.
  • 2014: Amin et al. (Brain) established in humans that intravenous PACAP-38 induces migraine-like attacks — turning the peptide from a physiological curiosity into a therapeutic target.
  • 2021: AMG 301, an antibody against the PAC1 receptor, tested in phase 2 for migraine prevention (Cephalalgia) — the first attempt to drug this pathway.
  • 2023: Lu AG09222 shown to block PACAP38-induced vasodilation, heart rate increase and headache in healthy subjects (J Headache Pain) — human proof of target engagement.
  • 2024: The HOPE phase 2 trial (NEJM) reported the first positive phase 2 result for PACAP-targeted migraine prevention: Lu AG09222 at 750 mg IV reduced monthly migraine days by 6.2 versus 4.2 on placebo (difference −2.0 days; 95% CI −3.8 to −0.3; P=0.02). This validated PACAP as a druggable target working independently of CGRP.
  • 2025: Eli Lilly's PACAP-neutralising antibody LY3451838 reported phase 1 and phase 2 data in treatment-resistant migraine (Cephalalgia). A randomised trial confirmed PACAP38-induced attacks occur independently of CGRP signalling.
  • 2026: Phase 2b PROCEED (NCT06323928, ~498 participants) met its primary endpoint for bocunebart (the development name for Lu AG09222); results presented at the American Headache Society meeting, with pivotal phase 3 planned. A Headache review framed the field as "PACAP blockade and the transformation of clinical practice."

Mechanism (as proposed)

PACAP binds PAC1, VPAC1 and VPAC2 receptors, coupling primarily to Gs and driving cAMP production with exceptional potency. In the trigeminovascular system this produces cranial vasodilation and activation and sensitisation of meningeal nociceptors — the sequence that underlies its ability to provoke migraine. Elsewhere in the nervous system, the same signalling supports the neurotrophic, neuroprotective and neurodevelopmental roles documented in cell and animal models, including interactions with BDNF signalling.

Both faces of this mechanism are real. PACAP genuinely is a neurotrophic signalling molecule with protective effects in preclinical models, and administering it to humans genuinely provokes headache and vasodilation. The second fact is the one with human trial data behind it.

Reading the evidence honestly

This entry has an unusual shape, so it is worth stating the structure plainly.

The strongest human evidence about PACAP is that giving it causes migraine. That finding is replicated, randomised, mechanistically characterised, and stable enough to be used as an experimental model for inducing attacks on demand. It is not an obscure side effect; it is the peptide's best-documented human effect.

The strongest therapeutic evidence is for blocking it. Every clinical programme in this space — bocunebart, LY3451838, AMG 301 — is an antibody that neutralises PACAP or its receptor. The A-grade clinical results in this entry belong to those antibodies. Citing "strong clinical evidence for PACAP" without specifying direction inverts what the trials found.

The neuroprotection story is preclinical. Cell and animal data supporting neurotrophic and neuroprotective effects are genuine and interesting. They have never been tested as a human therapy, and any attempt to do so would have to contend with the vascular and nociceptive effects that show up reliably at doses used in human provocation studies.

The overall grade reflects this: a physiologically important, well-characterised, mechanistically fascinating peptide, whose marketed use as a nootropic or neuroprotective agent has no human efficacy evidence and runs directly against the only well-established human findings about administering it.

Chemical identifiers

Cross-reference identifiers for the authoritative external databases — not a recipe, and nothing about how to use it.

UniProtP18509

via UniProt Swiss-Prot P18509 (human ADCYAP1) — the PACAP precursor, from which PACAP-38 and PACAP-27 are cleaved; no separate reviewed entry per form. DOIs resolved via NCBI E-utilities by PMID and Crossref (one supplied DOI title-verified). SMILES/InChIKey omitted for a 38-residue peptide. · high confidence

Sources — 8 cited
01Amin FM, Hougaard A, Schytz HW, et al. Investigation of the pathophysiological mechanisms of migraine attacks induced by pituitary adenylate cyclase-activating polypeptide-38. Brain. 2014;137:779-794.
02Ashina M, Phul R, Khodaie M, Löf E, Florea I. A monoclonal antibody to PACAP for migraine prevention. N Engl J Med. 2024.
03Al-Karagholi MA, Zhuang ZA, Beich S, Ashina H, Ashina M. PACAP38-induced migraine attacks are independent of CGRP signaling: a randomized controlled trial. J Headache Pain. 2025;26:79.
04Johnson MP, Krikke-Workel J, Patel CN, et al. Preclinical and clinical evaluation of LY3451838, a PACAP-neutralizing monoclonal antibody, in randomized, double-blind, placebo-controlled phase 1 and phase 2 studies. Cephalalgia. 2025;45:3331024251368757.
05Ashina M, Doležil D, Bonner JH, et al. A phase 2, randomized, double-blind, placebo-controlled trial of AMG 301, a PAC1 receptor monoclonal antibody for migraine prevention. Cephalalgia. 2021;41:33-44.
06Rasmussen NB, Deligianni C, Christensen CE, et al. The effect of Lu AG09222 on PACAP38- and VIP-induced vasodilation, heart rate increase, and headache in healthy subjects. J Headache Pain. 2023;24:60.
07Christensen RH, Strassman A, Ashina M, Ashina H, Burstein R. Activation and sensitization of meningeal nociceptors by PACAP-38: implications for migraine headache. Brain. 2026;149:897-907.
08Ashina M, et al. Pituitary adenylate cyclase-activating polypeptide blockade in migraine and the transformation of clinical practice. Headache. 2026.
Updated 2026-07-22 (the live development is anti-PACAP antibodies (bocunebart phase 3 planned 2H 2026) — re-check trial outcomes and any approval)

Grades reflect the published evidence, not our interest. No dosing, reconstitution, or administration is published for research compounds — that restraint is deliberate.

Related compounds
VIP (Vasoactive Intestinal Peptide)A
Peptide
SemaxC
Peptide
CerebrolysinC
Peptide
Davunetide (NAP)F
Peptide
Explore by goal
Neuro & cognitive
Vallydia

A neutral reference and a lawful-lane shop. Registered in Spain. Information for those who seek it — never promotion.

RegionUnited States
ExploreRegisterThe Register — full indexCategoriesTrust & COAHow we gradeOpen data
ShopCosmetic peptidesJournalQuizzes
TermsPrivacyCookiesReturnsShippingImprint

This site provides neutral scientific reference and sells only products lawful in your region. Nothing here is medical advice, a recommendation, or an offer to supply unapproved medicines. No dosing or administration is published for research compounds. Cosmetic peptides per Regulation (EC) 1223/2009. Unapproved injectable peptides are neither sold nor advertised in the EU (Directive 2001/83/EC, Title VIII). © 2026 Vallydia SL — Registered in Spain.

PACAP — evidence, uses & regulatory status · Vallydia