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Explore  /  Davunetide (NAP)
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Davunetide (NAP)

F
lead outcome
Progressive supranuclear palsy (PSP) — the…
grades vary by outcome ↓
Peptide
also called — NAP · AL-108 · CP201 · NAPVSIPQ · ADNP fragment (Asn-Ala-Pro-Val-Ser-Ile-Pro-Gln) · INCI: none
neuroprotection (investigational)microtubule stabilisationtau pathologycognition (investigational)

Status: reference entry — not for sale. No dosing, reconstitution, or administration is published (intentional). Neutral scientific reference only. Davunetide is an investigational drug, not a cosmetic ingredient and not a supplement.

In brief

Davunetide (NAP, AL-108) is an intranasal eight-amino-acid peptide (NAPVSIPQ) derived from activity-dependent neuroprotective protein (ADNP). Its preclinical case was unusually strong — it stabilises microtubules and lowers hyperphosphorylated tau in cell and mouse models — and it produced an encouraging small phase 2 signal on attention and working memory in mild cognitive impairment. It then received the cleanest possible human test: a 313-participant, 52-week, randomised, double-blind phase 2/3 trial in progressive supranuclear palsy, a pure tauopathy. It missed both co-primary endpoints, and the authors concluded it is not an effective treatment for PSP. That negative result is the defining fact of this entry. A later post-hoc reanalysis by the compound's inventor reported benefit in women specifically — an interesting hypothesis, but a subgroup rescue of a failed trial, not evidence. The one live programme is ADNP syndrome (a monogenic disorder where the rationale is more direct), with orphan designations in the US and EU; note that orphan status is granted for rarity, not efficacy, and that the reported 2024 phase 3 does not appear in trial registries. Approved nowhere, for anything.

Legal standing, by region
European Union
Not approved

No marketing authorisation anywhere in the EU. Holds EMA orphan medicinal product designation for ADNP syndrome — a development incentive, not an approval and not evidence of efficacy. Not eligible for magistral or officinal compounding. Any EU sale is as a non-medicinal "research" chemical, which does not authorise human use.

United Kingdom
Not approved

No marketing authorisation; investigational status only.

United States · your region
Not FDA-approved (investigational)

Investigational only. Holds FDA orphan drug designation (DRU-2017-6243) and rare pediatric disease designation for ADNP syndrome; both are incentive designations granted for rarity, not approvals. ALZFORUM lists FDA status as Inactive for mild cognitive impairment, PSP, schizophrenia and frontotemporal dementia, with autism spectrum disorder listed at phase 3.

International
Not approved anywhere

Approved in no jurisdiction for any indication. Development has been led successively by Allon Therapeutics, Paladin Labs and now ExoNavis Therapeutics.

Evidence, by outcome
How we grade →

An honest grade per outcome — drawn from the evidence, not any catalogue. Hype and undemonstrated marketing claims grade low.

OutcomeEvidence base · effectGrade
Progressive supranuclear palsy (PSP) — the definitive phase 2/3 trial
This is the single largest and most rigorous davunetide trial ever run, and it is unambiguously negative. Any claim of neuroprotective efficacy has to be read against this result, not around it.
Boxer AL, et al. Lancet Neurol 2014;13(7):676-685 (PMID 24873720) — randomised, double-blind, placebo-controlled phase 2/3 trial. 313 participants, 52 weeks, 48 centres across Australia, Canada, France, Germany, UK and USA. Co-primary endpoints: change from baseline in PSP Rating Scale (PSPRS) and Schwab & England Activities of Daily Living (SEADL). · No benefit. The trial missed both co-primary endpoints; the authors' stated conclusion is that davunetide is not an effective treatment for PSP.
F
Amnestic mild cognitive impairment (MCI) — attention / working memory
Small, short (12 weeks), and in a population that is heterogeneous by definition. A positive phase 2 signal that was never confirmed — and the later, far larger PSP trial in a related tauopathy failed outright. Treat as hypothesis-generating, not established.
Morimoto BH, et al. Dement Geriatr Cogn Disord 2013;35(5-6):322-336 — 12-week randomised, double-blind, placebo-controlled ascending-dose phase 2 study of intranasal AL-108 in 144 subjects with amnestic MCI. · Signals of benefit on attention and working memory measures; safety and tolerability acceptable.
C
Sex-dependent efficacy ("works in women") — post-hoc reanalysis
This is a post-hoc subgroup reanalysis of a trial that failed its pre-specified endpoints — the weakest form of clinical evidence, and the classic route by which negative trials are rescued narratively. It was not pre-specified, has not been replicated prospectively, and the senior author is the compound's named inventor and VP of Drug Development at the company licensing it. The finding may be real and worth testing; it is not, on this basis, established.
Gozes I, Shapira G, Lobyntseva A, Shomron N. Unexpected gender differences in progressive supranuclear palsy reveal efficacy for davunetide in women. Transl Psychiatry 2023;13:319 (PMID 37845254) — post-hoc reanalysis of the negative 2014 PSP trial cohort. · Reports faster deterioration in female placebo patients and a corresponding apparent davunetide benefit in women on PSPRS and SEADL.
D
Microtubule stabilisation / anti-tau (mechanism level)
A strong preclinical mechanism that did not translate: the PSP trial was the direct human test of exactly this mechanism in exactly the right disease, and it failed. Mechanism-level grade B does not transfer to clinical benefit.
Extensive preclinical work: cell culture neuroprotection against microtubule disruption and varied toxic insults; transgenic MAPT- mutant mouse models showing reduced hyperphosphorylated insoluble tau and improved Morris water-maze performance. Reviewed in Gozes et al., Adv Drug Deliv Rev 2025 (PMID 40185278). · Consistent, mechanistically coherent microtubule-stabilising and tau-lowering effects in vitro and in animal models.
B
Schizophrenia, frontotemporal dementia (development status)
Inactive status reflects programmes that stopped, not indications that were proven.
Programmes explored and discontinued; ALZFORUM lists US FDA status for mild cognitive impairment, PSP, schizophrenia and frontotemporal dementia as Inactive. · Not established for any of these indications.
ADNP syndrome (the current programme)
Two things worth stating plainly. First, ALZFORUM notes this phase 3 trial does not appear in clinical trial registries — an unusual gap for a study of that description. Second, orphan and rare-pediatric designations are regulatory incentives granted on the basis of the condition's rarity, not evidence that the drug works. Neither is an efficacy signal. This is the one live programme, and the rationale (replacing the function of a mutated gene product in a monogenic disorder) is more targeted than the adult neurodegeneration attempts — but nothing is published.
ExoNavis Therapeutics licensed davunetide from Tel Aviv University in 2021. Per the company, a phase 3 trial in 97 children with ADNP mutations began in October 2024. Davunetide holds US FDA orphan drug and rare pediatric disease designation (DRU-2017-6243) and EMA orphan medicinal product designation for ADNP syndrome. · No results published.
Human safety & tolerability
Safety data are reasonable for a compound of this stage, but exposure is limited to trial settings and durations. Long-term safety is not characterised, and gray-market material carries separate purity and sterility risks that have nothing to do with the trial data.
Intranasal administration was well tolerated across the MCI phase 2 and the 52-week PSP phase 2/3 (313 participants), with acceptable safety reported. · No major safety signal in the published trials.
Disclosure

Vallydia sells its own cosmetic serums, and some ingredients graded here belong to the same categories as those products. Grades are drawn from the published evidence by the method we publish, and applied to our own ingredients on the same terms — our copper-peptide serum is graded no more kindly than the peptides it competes with. We disclose the interest so you can weigh it.

Trade names shown here (for example Matrixyl, Argireline, Syn-Ake) are the property of their respective owners and are used only to identify the ingredient under discussion. Their appearance implies no affiliation with, or endorsement by, the proprietor.

Evidence changes

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Identity

Davunetide — also known as NAP, AL-108 and CP201 — is a synthetic eight-amino-acid peptide with the sequence NAPVSIPQ (Asn-Ala-Pro-Val-Ser-Ile-Pro-Gln). It is the active fragment of activity-dependent neuroprotective protein (ADNP), a protein released by glial cells in response to vasoactive intestinal peptide and essential for normal brain development. ADNP is one of the more frequently mutated genes in syndromic autism, and somatic ADNP mutations have been described in Alzheimer's disease — which is the thread linking davunetide's otherwise scattered list of attempted indications. It has been developed for intranasal administration throughout.

Development & history

  • 1990s–2000s: ADNP and its active NAP fragment characterised by Illana Gozes and colleagues at Tel Aviv University. Preclinical work established microtubule stabilisation as the proposed mechanism, with neuroprotection across varied toxic insults in cell culture and reduced tau pathology in MAPT-mutant mouse models.
  • 2007–2008: Developed clinically by Allon Therapeutics (Canada) as AL-108 (intranasal) and AL-208 (intravenous), positioned as a tau-directed neuroprotective agent.
  • 2013: Phase 2 in amnestic mild cognitive impairment published (Morimoto et al.) — 144 subjects, 12 weeks intranasal, signals on attention and working memory, acceptable tolerability. This was the result that justified moving to a larger trial.
  • 2010–2012: The pivotal phase 2/3 trial in progressive supranuclear palsy ran at 48 centres in six countries — 313 participants randomised 1:1 to 30 mg intranasal twice daily or placebo for 52 weeks.
  • 2014: Results published in Lancet Neurol (Boxer et al.). The trial missed both co-primary endpoints (PSPRS and SEADL). The authors' conclusion was that davunetide is not an effective treatment for PSP, while noting that disease-modifying trials in PSP are feasible and should continue with other tau-directed candidates. Allon's programme did not recover; the compound passed through Paladin Labs.
  • 2021: ExoNavis Therapeutics licensed davunetide from Tel Aviv University, refocusing it on ADNP syndrome — a rare monogenic disorder in which the rationale is replacement of a deficient gene product rather than modification of a complex late-onset disease.
  • 2023: A post-hoc reanalysis of the PSP cohort (Gozes et al., Transl Psychiatry) reported that female participants deteriorated faster on placebo and that davunetide appeared to benefit women. Widely cited since as evidence the drug "works in women."
  • 2024: ExoNavis states a phase 3 trial in 97 children with ADNP mutations began in October. ALZFORUM notes the trial does not appear in clinical trial registries.
  • Designations: US FDA orphan drug (DRU-2017-6243) and rare pediatric disease designation; EMA orphan medicinal product designation — all for ADNP syndrome, all granted on the basis of rarity rather than demonstrated efficacy.

Mechanism (as proposed)

Davunetide's proposed mechanism is microtubule stabilisation. The peptide interacts with tubulin and with microtubule end-binding proteins, supporting the microtubule network that neurons depend on for axonal transport, cell morphology and synaptic function. Because tau's normal job is stabilising microtubules — and because tauopathies are diseases in which that stabilisation fails and hyperphosphorylated tau accumulates — a peptide that stabilises microtubules directly is a coherent therapeutic idea. In preclinical models this played out as expected: reduced tau hyperphosphorylation, less insoluble tau, protection against microtubule-disrupting insults, and improved behavioural performance in MAPT-mutant mice.

The honest reading is that this mechanism was tested in humans in the most favourable possible setting and did not deliver. Progressive supranuclear palsy is a "pure" tauopathy — the cleanest available human test of an anti-tau, microtubule-stabilising agent — and a well-powered, well-run, 52-week randomised trial found no benefit on either co-primary endpoint. A coherent mechanism with strong animal data that fails its direct human test is a common pattern in neurodegeneration drug development, and davunetide is one of its clearer examples.

Reading the evidence honestly

Three points are worth separating, because they are routinely blurred when davunetide is discussed outside the literature.

The negative trial is the main fact. It was large by neurodegeneration standards, international, double-blind, placebo-controlled, and 52 weeks long. It failed. Sources that lead with "clinical studies have demonstrated safety, favourable bioavailability and potential efficacy" are not describing that trial's outcome.

The "efficacy in women" claim is a post-hoc subgroup analysis of that failed trial. Post-hoc subgroup findings are the weakest tier of clinical evidence and the standard mechanism by which failed trials acquire a second life. It is a legitimate hypothesis worth prospective testing. It is not a demonstrated effect, it has not been replicated in a trial designed to test it, and its senior author is the compound's named inventor and an officer of the company that licensed it — a conflict that should be visible when weighing the claim, not hidden.

Orphan designation is not evidence. FDA orphan drug status, rare pediatric disease designation and EMA orphan medicinal product status are incentives to develop treatments for rare conditions. They are awarded on the basis of the disease's rarity and a plausible rationale, before efficacy is shown. Citing them as validation inverts what they mean.

None of this makes davunetide worthless. The ADNP syndrome programme has a more defensible rationale than the adult neurodegeneration attempts, the safety record across trials is unremarkable in the good sense, and the mechanism remains interesting. But the compound's grade reflects where the human evidence actually stands: one clean negative trial in the disease it was best suited to, one small unreplicated positive signal, and one live programme with nothing published and an unregistered trial.

Chemical identifiers

Cross-reference identifiers for the authoritative external databases — not a recipe, and nothing about how to use it.

PubChem CID9832404
InChIKeyDWLTUUXCVGVRAV-XWRHUKJGSA-N
SMILESCC[C@H](C)[C@@H](C(=O)N1CCC[C@H]1C(=O)N[C@@H](CCC(=O)N)C(=O)O)NC(=O)[C@H](CO)NC(=O)[C@H](C(C)C)NC(=O)[C@@H]2CCCN2C(=O)[C@H](C)NC(=O)[C@H](CC(=O)N)N
DrugBankDB12613

via PubChem exact-name match (davunetide, CID 9832404); DOIs via NCBI E-utilities by PMID · high confidence

Sources — 6 cited
01Boxer AL, Lang AE, Grossman M, Knopman DS, Miller BL, Schneider LS, et al. Davunetide in patients with progressive supranuclear palsy: a randomised, double-blind, placebo-controlled phase 2/3 trial. Lancet Neurol. 2014;13(7):676-685.
02Morimoto BH, Schmechel D, Hirman J, Blackwell A, Keith J, Gold M, et al. A double-blind, placebo-controlled, ascending-dose, randomized study to evaluate the safety, tolerability and effects on cognition of AL-108 after 12 weeks of intranasal administration in subjects with mild cognitive impairment. Dement Geriatr Cogn Disord. 2013;35(5-6):322-336.
03Gozes I, Shapira G, Lobyntseva A, Shomron N. Unexpected gender differences in progressive supranuclear palsy reveal efficacy for davunetide in women. Transl Psychiatry. 2023;13(1):319.
04Gozes I, et al. Intranasal NAP (davunetide): neuroprotection and circadian rhythmicity. Adv Drug Deliv Rev. 2025 (PMID 40185278).
05Tariot PN. Commentary on the davunetide PSP trial. Lancet Neurol. 2014;13(7):641-643.
06ALZFORUM therapeutics entry: Davunetide (development history, regulatory status, and note that the 2024 ExoNavis phase 3 does not appear in trial registries).
Updated 2026-07-22 (the live programme is ADNP syndrome under ExoNavis — re-check whether the phase 3 appears in a registry and whether any results are published)

Grades reflect the published evidence, not our interest. No dosing, reconstitution, or administration is published for research compounds — that restraint is deliberate.

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Davunetide (NAP) — evidence, uses & regulatory status · Vallydia