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Octinoxate (Ethylhexyl Methoxycinnamate)

C
lead outcome
Overall as a sunscreen UV filter
grades vary by outcome ↓
Small molecule (non-peptide)
also called — ethylhexyl methoxycinnamate · EHMC · octyl methoxycinnamate · OMC · 2-ethylhexyl-4-methoxycinnamate · Neo Heliopan AV
UV filter (organic)UVB protectionendocrine-activity concernenvironmental concern

Status: reference entry — not for sale. Neutral scientific reference only. No application instructions are published here; concentration figures are regulatory ceilings, not usage advice.

In brief

Octinoxate (INCI ethylhexyl methoxycinnamate, also OMC or EHMC) was for decades the most widely used UVB filter in the world — present in over 90% of personal care products in one survey — chosen for its spreadability and non-greasy finish. Three things count against it. It offers no UVA protection whatsoever, so it always depends on partner filters. It is photounstable, losing absorption capacity through photoisomerization unless stabilised. And it has one of the more substantial endocrine files of any filter: estrogenic, anti-progestogenic and anti-thyroid activity reported across species, with detection in human urine, blood and breast milk. One correction to the usual framing, though: octinoxate and oxybenzone are treated as a single unit by the bans and the discourse, but on systemic absorption octinoxate is the lower of the two, and some authors describe it as the safer on that basis. It also has unusually low sensitisation potential, outperforming octocrylene, oxybenzone and avobenzone on allergy. The review literature states plainly that no scientific consensus exists on its use — and the market has moved anyway, with usage reportedly down around 70% between 2020 and 2025.

Legal standing, by region
European Union
Permitted up to 10%, under review

Listed in Annex VI of the EU Cosmetic Products Regulation (EC) No 1223/2009 at a maximum of 10%. The European Commission raised concerns about endocrine disruption and genotoxicity in 2024; restrictions are under review.

United Kingdom
Permitted up to 10%

Retained EU cosmetics framework; equivalent to the EU position.

United States
OTC drug — permitted up to 7.5%, Category III

Permitted at up to 7.5%. The FDA has not reached a final GRASE determination and has requested additional safety data. **Banned at local level:** Hawaii, Key West, the US Virgin Islands (sale and use, March 2020), and further Florida jurisdictions including Miami Beach.

International
Permitted with wide variation; banned in several island jurisdictions

**Japan permits up to 20% — the highest limit globally.** Australia up to 10%; Canada up to 7.5%. Banned alongside oxybenzone in Palau, Aruba, Bonaire and other reef jurisdictions. Market use has fallen sharply — one estimate puts the reduction at around 70% between 2020 and 2025, driven by consumer demand rather than regulation.

Evidence, by outcome
How we grade →

An honest grade per outcome — drawn from the evidence, not any catalogue. Hype and undemonstrated marketing claims grade low.

OutcomeEvidence base · effectGrade
Overall as a sunscreen UV filter
Read the rows for the split, including where octinoxate quietly outperforms: lower systemic absorption than oxybenzone, and low sensitisation potential. The concern rows are graded D where the evidence is substantial but unsettled, not where harm is demonstrated. The C weights the whole — and better-profiled filters now exist.
Octinoxate is an effective, cosmetically elegant UVB filter (grade B, next row) but a narrow one: it provides **no UVA protection at all**, it is photounstable, and it has one of the more substantial endocrine files of any filter — with genuinely unsettled human relevance. The market has already largely moved away from it. The overall grade reflects a competent but concern-laden filter that no longer earns its historical dominance. · A once-ubiquitous UVB filter now in steep decline, weighed down by no-UVA coverage, photoinstability and a substantial (unsettled) endocrine file.
C
UVB protection
**It provides no UVA protection at all** — not long UVA, not short UVA. Any octinoxate product depends entirely on its partner filters for UVA coverage, and a high SPF from octinoxate alone means sunburn protection without photoageing protection. It is also less potent than some alternatives, requiring higher concentrations.
A cinnamate ester absorbing UVB across roughly 290-320 nm with peak absorption at **311 nm**. Historically the most widely used UVB filter — detected in over 90% of commercially available personal care products in one 2008 survey — valued for excellent spreadability and a non-greasy finish. · Effective, cosmetically elegant UVB filtering.
B
Photostability
A second, less obvious problem: in phototoxicity testing, avobenzone- octinoxate combinations showed phototoxic potential — so the pairing that would seem to solve octinoxate's lack of UVA introduces its own issue unless properly stabilised. Bemotrizinol is documented as keeping both avobenzone and octinoxate active across sustained exposure.
Octinoxate undergoes **photoisomerization** under UV exposure, altering its molecular structure and diminishing its UV absorption capacity over time. It requires stabilisers or frequent reapplication to maintain performance. · Protection declines during sun exposure unless the formula addresses it.
D
Endocrine activity
The review literature is explicit that **there is still no consensus in the scientific community** about its use, and the human studies that exist are largely associational. This is a compound with a genuinely substantial concern file and genuinely unsettled human relevance — not a case where either "proven harmful" or "cleared" is accurate.
One of the more extensively studied filters in this respect. Reported effects across species include **estrogenic, anti-progestogenic and anti-thyroid activity** (reviewed in Lorigo et al., 2018). A dedicated investigation combining in vivo and in vitro data examined octinoxate as a potential thyroid hormone disruptor. Epidemiological, ex vivo and in vitro human studies have reported cardiovascular, thyroid, reproductive and immunological effects. Detected in human urine, blood and breast milk. · Consistent endocrine activity signals in laboratory and animal systems, with human data suggestive but not conclusive.
D
Systemic absorption
This is the most-missed distinction in the "oxybenzone and octinoxate" pairing, which the bans and the discourse treat as a single unit. On absorption they are not equivalent: oxybenzone is the more absorbed and more universally detected of the two. Octinoxate's concern profile is weighted toward endocrine activity and photoinstability rather than sheer exposure.
Lipophilic and absorbed through skin into the circulation without hepatic first-pass metabolism. Detected in urine, blood and breast milk in human biomonitoring. **However**, compared with other filters — benzophenone-3 in particular — octinoxate shows **lower dermal penetration and systemic absorption**, on which basis some authors describe it as the safer of the two. · Absorbed, but less so than oxybenzone.
C
Environmental and coral effects
The same methodological critique that applies to the oxybenzone coral literature applies here — the studies underpinning the bans have been criticised in the peer-reviewed literature for design flaws, and that critique carries industry affiliations of its own. And the same attribution point stands: **climate change is the dominant driver of coral decline**, with sunscreen a local-scale contributor at most.
Octinoxate is among the filters banned for reef protection alongside oxybenzone. Coral exposure is reported to cause bleaching events, and UV filters including octinoxate have been reported to increase viral abundance in marine bacterioplankton through prophage induction — a microbial-ecosystem effect distinct from direct coral toxicity. It is poorly removed by water treatment and enters rivers and oceans. · Documented laboratory effects on corals and marine microbial ecology.
D
Skin sensitisation
Worth stating because it is the one area where octinoxate outperforms several better-regarded filters. Octocrylene, oxybenzone and avobenzone are all more commonly implicated in photocontact allergy.
Noted as having low potential to sensitise skin or act as a photoallergen — unusually good among organic filters in this respect. · Rarely causes contact or photocontact allergy.
Disclosure

Vallydia sells its own cosmetic serums, and some ingredients graded here belong to the same categories as those products. Grades are drawn from the published evidence by the method we publish, and applied to our own ingredients on the same terms — our copper-peptide serum is graded no more kindly than the peptides it competes with. We disclose the interest so you can weigh it.

Trade names shown here (for example Matrixyl, Argireline, Syn-Ake) are the property of their respective owners and are used only to identify the ingredient under discussion. Their appearance implies no affiliation with, or endorsement by, the proprietor.

Evidence changes

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Identity

Octinoxate — INCI name ethylhexyl methoxycinnamate, also known as octyl methoxycinnamate (OMC) or EHMC — is a cinnamate ester UVB filter. It has been the most widely used UVB filter in cosmetics for decades, appearing not only in sunscreens but in hair colour, shampoos, lipsticks, nail polish and creams, where it also serves to protect the product from UV degradation.

⚠️ The "oct-" cluster is a common source of error. Octinoxate (a cinnamate), octocrylene (also a cinnamate derivative, different molecule), and octisalate (ethylhexyl salicylate, a salicylate) are three separate filters with similar names.

What it does, and what it does not

Octinoxate absorbs UVB across roughly 290-320 nm, peaking at 311 nm. It is cosmetically excellent — spreadable, non-greasy — which is a large part of why it dominated formulation for so long.

It provides no UVA protection. Not long UVA, not short UVA. This is the single most important practical fact about it: a product relying on octinoxate for its SPF is protecting against sunburn while leaving the wavelengths responsible for photoageing and pigmentation entirely to whatever else is in the formula.

It is also photounstable, degrading via photoisomerization — UV exposure alters its molecular structure and reduces its absorption capacity. Unlike avobenzone's tautomerism, which has well-established stabilisation routes, octinoxate's instability is usually managed by reapplication or by pairing with photostable filters such as bemotrizinol, which is documented as keeping both avobenzone and octinoxate active through sustained exposure.

One further formulation trap: avobenzone-octinoxate combinations have shown phototoxic potential in testing. Pairing them to cover the UVA gap is not automatically safe without proper stabilisation.

Reading the evidence honestly

The endocrine file is substantial, and it is not settled. Estrogenic, anti-progestogenic and anti-thyroid activity have been reported across species; a dedicated study combined in vivo and in vitro data on thyroid hormone disruption; epidemiological, ex vivo and in vitro human work has reported cardiovascular, thyroid, reproductive and immunological effects; and it is detected in human urine, blood and breast milk. The review literature states directly that no consensus exists in the scientific community about its use. That is the honest position — not exoneration, and not proof of harm.

The correction worth making. Octinoxate and oxybenzone are treated as a matched pair by regulation and by public discussion — banned together, discussed together, avoided together. On systemic absorption they are not equivalent: octinoxate shows lower dermal penetration and lower systemic absorption than benzophenone-3, and at least one review describes it as the safer of the two on that basis. Its concerns are weighted toward endocrine activity and photoinstability; oxybenzone's toward sheer exposure. Lumping them obscures a real difference.

Where it quietly outperforms. Octinoxate has notably low sensitisation potential — it rarely causes contact or photocontact allergy, unlike octocrylene, oxybenzone and avobenzone. For someone whose problem with sunscreen is reactions rather than theoretical endocrine concerns, that is not a trivial point.

On the environment. Octinoxate is banned alongside oxybenzone in Hawaii, Key West, the US Virgin Islands, Palau, Aruba, Bonaire and elsewhere. The coral-toxicity evidence carries the same methodological criticism documented on the oxybenzone entry, and the same attribution caveat applies: climate change is the dominant driver of coral decline. There is also a distinct finding worth knowing — UV filters including octinoxate have been reported to increase viral abundance in marine bacterioplankton through prophage induction, an ecosystem-level effect separate from direct coral toxicity.

A scale note that rarely gets made. Because octinoxate appears in around 90% of personal care products historically, a full ban would remove an enormous share of the cosmetic market — a practical consideration that the literature raises explicitly, and one that has shaped regulatory caution as much as the science has.

And the market moved first. Reported usage fell around 70% between 2020 and 2025, driven by consumer demand rather than by any regulatory determination — the FDA still has not reached a GRASE conclusion, and the EU review continues. As with oxybenzone, the practical argument has become less about litigating the controversy and more about the availability of better filters: bemotrizinol, DHHB and ethylhexyl triazone all outperform it on spectrum, photostability, or both.

Chemical identifiers

Cross-reference identifiers for the authoritative external databases — not a recipe, and nothing about how to use it.

PubChem CID5355130
InChIKeyYBGZDTIWKVFICR-JLHYYAGUSA-N
SMILESCCCCC(CC)COC(=O)C=CC1=CC=C(C=C1)OC

via PubChem exact-name match (octinoxate / ethylhexyl methoxycinnamate / octyl methoxycinnamate, CID 5355130; C18H26O3, the (E)-isomer); CAS 5466-77-3. Distinct from octocrylene (also a cinnamate derivative) and octisalate (ethylhexyl salicylate) — the "oct-" prefix cluster is a common error. · high confidence

Sources — 6 cited
01Exposure to UV-B filter octylmethoxycinnamate and human health effects: focus on endocrine disruptor actions. Sci Total Environ. 2024 — review of epidemiological, ex vivo and in vitro human data; notes absence of scientific consensus.
02Octinoxate as a potential thyroid hormone disruptor — a combination of in vivo and in vitro data. Sci Total Environ. 2022;854:159074.
03Lorigo M, et al. (2018) — review of endocrine-disrupting effects of OMC across species (estrogenic, anti-progestogenic, anti-thyroid).
04Janjua NR, et al. Systemic absorption of the sunscreens benzophenone-3, octyl-methoxycinnamate and 3-(4-methyl-benzylidene) camphor.
05Polycystic ovary syndrome (PCOS)-specific risk appraisal of the sunscreen UV filters oxybenzone/octinoxate. (PMC12656294)
06Miller IB, et al. Towards the development of standardized bioassays for corals: acute toxicity of the UV filter benzophenone-3 to scleractinian coral larvae. Toxics. 2022;10(5):244 (PMC9146638) — methodological critique applying to this filter's ban evidence too.
Updated 2026-07-25 (the EU review following the 2024 Commission concerns is the main moving part — re-check whether restrictions are adopted, and whether FDA reaches a GRASE determination)

Grades reflect the published evidence, not our interest. No dosing, reconstitution, or administration is published for research compounds — that restraint is deliberate.

Related compounds
Oxybenzone (Benzophenone-3)C
Small molecule (non-peptide)
AvobenzoneB
Small molecule (non-peptide)
Bemotrizinol (Tinosorb S)A
Small molecule (non-peptide)
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